I'm going to make an educated guess and say no. Here's my reasoning:
Consider the difficulty in just communicating with a satellite. See What is a link budget, and how do I make one? or What gain do I need to talk to SO-50 with my HT?
Geostationary orbit is much farther away than SO-50 and thus requires more gain, or more power.
Now if we are using this as a passive reflector, reasonable assumptions are that:
- even with a pretty high gain antenna, most of our transmitted energy will miss the satellite.
- most of the reflected energy won't be reflected back at the intended receiver back on Earth.
We can estimate both of these effects. Let's say we are transmitting with an isotropic antenna. (We wouldn't actually, but we can then work backwards to figure out how much gain we would need actually). Say we transmit with 1W. Any sphere centered on that transmitter will have 1W of power in it. By the time that sphere reaches the satellite at geostationary orbit, the sphere will be 35,786km in radius, and its area will be:
$$ A = 4 \pi (35786km)^2 \approx 1.6 \cdot 10^{16} m^2 $$
Thus, our power density at geostationary orbit is
$$ \frac{1W}{1.6 \cdot 10^{16} m^2} = \frac{6.3 \cdot 10^{-17}W}{m^2} $$
How much of this might be intercepted? Let's say we have something really big, like Envisat. It's largest face is 26m by 10m, for an area of $260m^2$. Let's say everyone is launching huge satellites into geostationary orbit for us to use as reflectors, and we can hit 100 of them. We then have an area of $26000m^2$ to intercept our transmission. Given our power density at that distance, the power intercepted is then:
$$ \require{cancel} \frac{6.3 \cdot 10^{-17}W}{\cancel{m^2}} \cdot 26000\cancel{m^2}
\approx 1.6 \cdot 10^{-12}W $$
Compared to the 1W we were transmitting with, our loss is:
$$ 10 \cdot \log_{10} \frac{1.6 \cdot 10^{-12}W}{1W} \approx -118dB $$
You can make up for some of this with antenna gain. You can increase transmitter power. But then, you have to have enough power left to communicate from the satellite reflectors back to Earth, which is a similar problem to talking to an ordinary communication satellite. Only, you must do it without the benefit of antenna gain on the satellite, since they are just pieces of trash unlikely to be pointed in the right direction. Plus, they probably aren't very efficient reflectors.
Say you transmit with 1000W and have a 40dBi antenna. The reflected signal is like a transmitter with an isotropic antenna in geostationary orbit with a power of:
$$ 1000W \cdot 10^{(-118dB + 40dB)/10} = 0.015mW $$
Do you think you could hit a satellite without any antenna gain and 0.015mW? I'm thinking no.
This might seem an odd conclusion, when moon bounce and meteor scatter work. However, the problem is that satellites in geostationary orbit have such a tiny angular diameter compared to the moon or the ionization left by meteors. There simply isn't enough area up there to intercept RF energy, so most of it goes uselessly into space.