I was reading this paper and I found it very interesting and the following question came up,
What are the main applications (what is used for) 100 GHz band?
I couldn't find any reference on what is used nowadays.
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Aside from what Zeiss Ikon wrote, these high frequencies are indeed also interesting for communications technology, for very high-rate and typically narrow-range links.
For example, in cellular mobile communications ("phones"), 5G specifies the "New Radio", which includes using several mmWave bands, the highest among them spanning 37 – 40 GHz.
The motivation is actually a bit complex, but mostly
Also, for long range links in space, especially inter-satellite links, going as high as 100 GHz does make sense for exactly Zeiss' reasons: The smaller the wavelength, the narrower the beam an antenna (array/dish) of fixed size can achieve. The math works out that this effect is exactly the same in magnitude as the increase of free space path loss (if you keep antenna system size constant and just change wavelength). If you have a dynamic constellation of satellites, you'll need digitally steerable antennas – and then, going for higher frequencies simply gives you the freedom to do exactly that.
A frequency of 100 GHz is equivalent to a 3 mm wavelength; these "millimeter waves" have been used for decades in airborne radars. The short wavelength allows a narrow beam and excellent gain from a dish that can fit inside the nose of a fighter aircraft, allowing a forward-looking radar with mechanical sweep to be used without disturbing the aerodynamics of a potentially supersonic airplane.
More modern radars use phased arrays (eliminating the need to physically move a dish, replacing it with an array of small flat panels and beam focusing and steering done by precisely delaying the signal to various portions of the array), but the same size limitations apply; shorter wavelengths allow smaller arrays to give required gain and beam spread for the application.
Emissions around this wavelength are used by millimeter wave scanners, of the sort you may have encountered in airport security.
Radiation in this band is useful because it penetrates clothing quite well, but skin not so much. This means the scanner can see contraband hidden under clothing.